Effect of Vulcanization System on the Structure and Properties of Polymer-Elastomer Composite Materials

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Abstract

The effect of vulcanization system on the properties of polymer-elastomer composite materials based on nitrile-butadiene rubber and ultrahigh molecular weight polyethylene is studied. An analysis of the rheometric and vulcanization characteristics of rubber compounds shows that, in the case of combined sulfur-peroxide vulcanization system, the crosslinking density of vulcanizates increases considerably. The study of the elastic and strength behavior and dynamic mechanical properties of the vulcanizates demonstrates that the sulfur-peroxide vulcanization system provides the best parameters, in particular at low temperatures. An examination of elastic and hysteresis properties of the samples before and after vulcanization, which are measured under dynamic loading in a wide frequency and strain range, allows one to describe the features of physicochemical interactions in polymer-elastomer materials depending on the used vulcanization system. The supramolecular structure of the vulcanizates is visualized by scanning electron microscopy, and chemical interaction between macromolecules of nitrile-butadiene rubber and ultrahigh molecular weight polyethylene occurring during peroxide vulcanization is proved by IR spectroscopy.

About the authors

N. V. Shadrinov

Institute of Oil and Gas Problems, Siberian Branch, Russian Academy of Sciences

Email: nshadrinov@gmail.com
677007, Yakutsk, Russia

A. R. Khaldeeva

Institute of Oil and Gas Problems, Siberian Branch, Russian Academy of Sciences

Email: nshadrinov@gmail.com
677007, Yakutsk, Russia

A. L. Fedorov

Institute of Oil and Gas Problems, Siberian Branch, Russian Academy of Sciences

Email: nshadrinov@gmail.com
677007, Yakutsk, Russia

M. N. Kondakov

Institute of Oil and Gas Problems, Siberian Branch, Russian Academy of Sciences

Email: nshadrinov@gmail.com
677007, Yakutsk, Russia

M. D. Sokolova

Institute of Oil and Gas Problems, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: nshadrinov@gmail.com
677007, Yakutsk, Russia

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Copyright (c) 2023 Н.В. Шадринов, А.Р. Халдеева, А.Л. Федоров, М.Н. Кондаков, М.Д. Соколова