Structure and Activity of Catalytic Systems Synthesized by Precipitation in Subcritical Water in the Fischer–Tropsch Liquid-Phase Synthesis

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Abstract

Modern developments in the field of creating fuels from alternative sources are aimed at producing liquid gasoline-type hydrocarbons with high yield. Fischer–Tropsch synthesis (FTS) is a well–known method for more than a hundred years that allows to obtain a wide range of hydrocarbons from carbon and hydrogen oxides. In this work, three metal-containing catalytic systems deposited on super-crosslinked polystyrene (HPS) have been synthesized (2% Fe– HPS, 1% Ru– HPS and 2% Fe–1% Ru– HPS) by precipitation in subcritical water, and their catalytic effect in the process of liquid-phase FTS was studied. The addition of Ru to the Fe-containing catalyst leads to an increase in the dispersion of active phase particles and, consequently, an increase in the activity of the catalytic system. The bimetallic catalyst 2% Fe–1% Ru–HPS showed a catalytic activity 1.5 times higher than that of the sample 2%Fe–HPS, selectivity with respect to alkanes C5–C11 was 98.5 mol. %. Based on data from kinetic experiments and physico-chemical studies of the bimetallic catalyst, a scheme for the liquid phase process was proposed. the Fischer–Tropsch synthesis.

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About the authors

M. E. Markova

Tver State Technical University; Tver State University

Author for correspondence.
Email: mashulikmarkova@gmail.com
Russian Federation, A. Nikitin str., 22, Tver, 170026; Zhelyabova str., 33, Tver, 170100

A. A. Stepacheva

Tver State Technical University

Email: mashulikmarkova@gmail.com
Russian Federation, A. Nikitin str., 22, Tver, 170026

A. V. Bykov

Tver State Technical University

Email: mashulikmarkova@gmail.com
Russian Federation, A. Nikitin str., 22, Tver, 170026

Y. V. Larichev

Boreskov Institute of Catalysis SB RAS

Email: mashulikmarkova@gmail.com
Russian Federation, Acad. Lavrentieva ave., 5, Novosibirsk, 630090

V. Y. Doluda

Tver State Technical University

Email: mashulikmarkova@gmail.com
Russian Federation, A. Nikitin str., 22, Tver, 170026

O. P. Tkachenko

N.D. Zelinsky Institute of Organic Chemistry RAS

Email: mashulikmarkova@gmail.com
Russian Federation, Leninsky prosp., 47, Moscow, 119991

M. G. Sulman

Tver State Technical University

Email: mashulikmarkova@gmail.com
Russian Federation, A. Nikitin str., 22, Tver, 170026

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Supplementary files

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2. Fig. 1. Particle size distribution obtained by SAXS for 2% Fe–SPS, 1% Ru–SPS and 2% Fe–1% Ru–SPS samples.

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3. Rice. 2. X-ray diffraction patterns of samples: SPS and 1% Ru–SPS (a), 2% Fe–1% Ru–SPS (b), and 10% Fe–1% Ru–SPS (c).

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4. Fig. 3. High-resolution spectra for the Fe2p and Ru3d sublevels for the 2% Fe–SPS (a), 1% Ru–SPS (b), 2% Fe–1% Ru–SPS (c, d) and 2% Fe–1% Ru–SPS-ref (d, f) samples.

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5. Fig. 4. IR diffuse reflectance spectra of CO adsorption for samples of 1% Ru–SPS (a), 2% Fe–SPS (b) and 2% Fe–1% Ru–SPS (c).

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6. Fig. 5. Kinetic curves of CO (a) and H2 (b) consumption in the Fischer–Tropsch synthesis in the presence of 1% Ru–SPS, 2% Fe–SPS and 2% Fe–1% Ru–SPS catalysts.

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7. Fig. 6. Curves of formation of liquid-phase Fischer–Tropsch synthesis products in the presence of 2% Fe–SPS (a), 1% Ru–SPS (b), 2% Fe–1% Ru–SPS (c) after 1.5 (●), 3 (○), 6 (▼) and 9 h (∆) from the beginning of the experiment.

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8. Scheme 1. Scheme of liquid-phase Fischer–Tropsch synthesis.

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