Effects of the microstructure of carbon materials under ion-beam surface modification

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Resumo

The effect of high-fluence (>1018 cm–2) irradiation by helium and argon ions with energy of 30 keV on the structure and morphology of the surface of carbon materials with significantly different microstructure: highly oriented pyrolytic graphite, glassy carbon, carbon fibres from PAN and viscose has been studied experimentally.

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Sobre autores

N. Andrianova

Moscow State University; Moscow Aviation Institute (National Research University)

Email: ov.mikhail@gmail.com

Skobeltsyn Institute of Nuclear Physics, Moscow State University

Rússia, Moscow, 119991; Moscow, 125993

A. Borisov

Moscow State University; Moscow Aviation Institute (National Research University); Moscow State Technological University “STANKIN”

Email: ov.mikhail@gmail.com

Skobeltsyn Institute of Nuclear Physics, Moscow State University

Rússia, Moscow, 119991; Moscow, 125993; Moscow, 127055

E. Vorobyeva

Moscow State University

Email: ov.mikhail@gmail.com

Skobeltsyn Institute of Nuclear Physics

Rússia, Moscow, 119991

M. Ovchinnikov

Moscow State University

Autor responsável pela correspondência
Email: ov.mikhail@gmail.com

Skobeltsyn Institute of Nuclear Physics

Rússia, Moscow, 119991

V. Sleptsov

Moscow Aviation Institute (National Research University)

Email: ov.mikhail@gmail.com
Rússia, Moscow, 125993

R. Tsyrkov

Moscow Aviation Institute (National Research University)

Email: ov.mikhail@gmail.com
Rússia, Moscow, 125993

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2. Fig. 1. SEM images of ion-induced morphology after irradiation with helium (a, b, c, d) and argon (d, f, g, h) ions with an energy of 30 keV of HOPG UPV-1T (a, d), carbon fibers VMN-4 (b, f), carbon fabric TGN-2MK (c, g) and glassy carbon SU-2500 (d, h). The irradiation fluence for HOPG and glassy carbon was 1018 cm–2, for carbon fibers >3⋅1018 cm–2. The irradiation temperature was above 200°C.

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3. Fig. 2. Raman spectra of carbon materials before (a) and after (b) high-dose irradiation with helium and argon ions with an energy of 30 keV.

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4. Fig. 3. SEM images of the HOPG surface morphology after irradiation with 30 keV helium ions at room temperature (a) and at 400°C (b, c). Fluence 1⋅1018 cm–2.

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5. Fig. 4. SEM images of the surface of PAN carbon fibers after irradiation with 15 keV argon ions (a) and 30 keV helium ions (b) at room temperature and a fluence of 3⋅1018 cm–2. SEM images of nanosized wall structures upon irradiation of HOPG (c) and SU-2500 glassy carbon (d) with 30 keV argon ions at temperatures of 400 and 500°C, respectively. Irradiation fluence is 1⋅1018 cm–2.

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