Propargyl-substituted furazanoazepines: synthesis, structure, enthalpy of formation, ballistic efficiency

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

7-Propargyl-7H-difurazano[3,4-b :3′,4′-f]furoxano[3″,4″-d]azepine (Az(O)Prg) and 7-propargyl-7H-trifurazano[3,4-b :3′,4′-d :3″,4″-f]azepine (AzPrg) as potential dispersants of solid fuels for gas-generating engines were synthesized for the first time. Their molecular structure, enthalpies of combustion and formation are determined. The relative aircraft flight range is estimated when using Az(O)Prg and AzPrg as fuel dispersants.

Толық мәтін

Рұқсат жабық

Авторлар туралы

D. Lempert

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: lempert@icp.ac.ru
Ресей, Chernogolovka

E. Ignatieva

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: lempert@icp.ac.ru
Ресей, Chernogolovka

A. Stepanov

“Tekhnolog” Special Design and Technological Bureau

Email: lempert@icp.ac.ru
Ресей, St. Petersburg

D. Dashko

“Tekhnolog” Special Design and Technological Bureau

Email: lempert@icp.ac.ru
Ресей, St. Petersburg

A. Kazakov

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: lempert@icp.ac.ru
Ресей, Chernogolovka

A. Nabatova

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: lempert@icp.ac.ru
Ресей, Chernogolovka

G. Shilov

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: lempert@icp.ac.ru
Ресей, Chernogolovka

G. Lagodzinskaya

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: lempert@icp.ac.ru
Ресей, Chernogolovka

D. Korchagin

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: lempert@icp.ac.ru
Ресей, Chernogolovka

S. Aldoshin

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: lempert@icp.ac.ru
Ресей, Chernogolovka

Әдебиет тізімі

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Жүктеу
2. Fig. 1. Molecular structure of AzPrg. Atoms are depicted as 50% probability ellipsoids. Hydrogen atoms are not labeled.

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3. Fig. 2. Packing of AzPrg crystal structure. Atoms are depicted as 50% probability ellipsoids.

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4. Fig. 3. Fragment of the crystal structure of AzPrg. Atoms are represented as ellipsoids of 50% probability. Dashed lines show van der Waals interactions (contacts).

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5. Fig. 4. Molecular structure of Az(O)Prg. Atoms are depicted as ellipsoids of 50% probability. Hydrogen atoms are not labeled.

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6. Fig. 5. Projection of the Az(O)Prg crystal structure onto a plane along the cell axis ab.

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7. Fig. 6. Energy and topology of the strongest pairwise intermolecular interactions in crystal structures: a - AzPrg, b - Az(O)Prg.

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