Spectral properties of tolan and its supramolecular complexes in solution and silicate hydrogel

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The complexation process of tolane and α-cyclodextrin in water, aqueous-ethanol solution and silicate hydrogel based on tetrakis(2 hydroxyethyl)orthosilicate was studied. The complex formation in solutions were confirmed by electron and 1H NMR spectroscopy, and the stability constant of the complex was determined using spectrofluorimetric titration (lgK1:1 = 1.5). The preservation of the inclusion complex during the preparation of the gel was confirmed by electron spectroscopy.

作者简介

G. Novitskii

Photochemistry Center of the Russian Academy of Sciences, Federal Research Center “Crystallography and Photonics” – National Research Center “Kurchatov Institute”

编辑信件的主要联系方式.
Email: georg.nov97@gmail.com
俄罗斯联邦, Moscow, 119421

A. Medvedeva

Photochemistry Center of the Russian Academy of Sciences, Federal Research Center “Crystallography and Photonics” – National Research Center “Kurchatov Institute”

Email: georg.nov97@gmail.com
俄罗斯联邦, Moscow, 119421

A. Koshkin

Photochemistry Center of the Russian Academy of Sciences, Federal Research Center “Crystallography and Photonics” – National Research Center “Kurchatov Institute”

Email: georg.nov97@gmail.com
俄罗斯联邦, Moscow, 119421

A. Vedernikov

Photochemistry Center of the Russian Academy of Sciences, Federal Research Center “Crystallography and Photonics” – National Research Center “Kurchatov Institute”

Email: georg.nov97@gmail.com
俄罗斯联邦, Moscow, 119421

N. Lobova

Photochemistry Center of the Russian Academy of Sciences, Federal Research Center “Crystallography and Photonics” – National Research Center “Kurchatov Institute”; Moscow Institute of Physics and Technology

Email: georg.nov97@gmail.com
俄罗斯联邦, Moscow, 119421; Dolgoprudny, 141701

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