Synthesis and structure of stibonium complexes: {[2,6-(MeO)2C6H3]3SbCH2C(O)OEt}I3 and {[(2,6-(MeO)2C6H3)3SbEt][Hg3I7]}n

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Аннотация

New stybonium complexes containing polyanions have been obtained. Alkylation of tris(2,6-dimethoxyphenyl)stibine with ethyl iodoacetic acid synthesized [Ar3SbCH2C(O)OEt]I3, Ar = 2,6-(MeO)2C6H3, which is also the product of the reaction of [Ar3SbCH2C(O)OEt]I and I2. The interaction of [Ar3SbEt]I with mercury diiodide leads to the formation of {[Ar3SbEt][Hg3I7]}n, Ar = 2,6-(MeO)2C6H3. The compounds [Ar3SbCH2C(O)OEt]I3 and {[Ar3SbEt][Hg3I7]}n were characterized by the by X-ray diffraction. Antimony and mercury atoms have a distorted tetrahedral coordination. Bond angles are in the ranges: ∠CSbC 104.2(2)–113.9(1)° and ∠CSbC 102.4(4)–116.0(5)°, ∠IHgI 97.06(2)–121.28(2)°.

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Авторлар туралы

I. Egorova

Blagoveschensk State Pedagogical University

Хат алмасуға жауапты Автор.
Email: bgpu.chim.egorova@mail.ru
Ресей, Blagoveschensk

I. Nesina

Blagoveschensk State Pedagogical University

Email: bgpu.chim.egorova@mail.ru
Ресей, Blagoveschensk

V. Zhidkov

Blagoveschensk State Pedagogical University

Email: bgpu.chim.egorova@mail.ru
Ресей, Blagoveschensk

N. Rodionova

Blagoveschensk State Pedagogical University

Email: bgpu.chim.egorova@mail.ru
Ресей, Blagoveschensk

N. Kuratieva

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: bgpu.chim.egorova@mail.ru
Ресей, Novosibirsk

N. Pervukhina

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: bgpu.chim.egorova@mail.ru
Ресей, Novosibirsk

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2. Scheme 1. Synthesis of stibonium complexes: a – ICH2C(O)OEt, a – ICH2C(O)OEt (t), b – EtI, c – HgI2, d – I2.

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3. Fig. 1. The structure of the cation of complex I with numbering of atoms and thermal vibration ellipsoids (50%), hydrogen atoms are not shown (a); projection of the structure of complex I onto the ac plane (b).

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4. Fig. 2. Structure of the cation of complex II with numbering of atoms and thermal vibration ellipsoids (50%), hydrogen atoms are not shown (a); fragment of the polymeric anion [Hg3I7]n (b).

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5. Fig. 3. Projection of a fragment of the structure of compound II along the c axis.

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