Zinc perfluorocyclohexanoate (C6F11COO)2Zn: synthesis, vapor formation and evaluation of thermodynamic characteristics

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Abstract

The heterophase reaction of interaction of silver perfluorocyclohexanoate with zinc was studied by TG, DSC and mass spectrometry. It was found that as a result of interaction in the temperature range of 320–520 K, solid zinc perfluorocyclohexanoate is formed and an intramolecular reaction of zinc fluoride formation occurs. The obtained experimental data allowed us to calculate the standard enthalpies of formation of the solid zinc complex ΔfН°298.15 = –5693 ± 29 kJ/mol, sublimation and formation of dimeric molecules Zn2(C6F11COO)4 ΔsН°Т = = 190±15 kJ/mol, ΔfН°Т = –11196 ± 40 kJ/mol.

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About the authors

I. P. Malkerova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119991

D. B. Kayumova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119991

D. S. Yambulatov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119991

A. V. Khoroshilov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119991

A. А. Sidorov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119991

A. S. Alikhanyan

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: alikhan@igic.ras.ru
Russian Federation, Moscow, 119991

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2. Fig. 1. Mass loss (wt%) and heat flux (mW/mg) upon heating Ag(C6F11COO) (DSC measurement in red; mass loss in intermittent blue).

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3. Fig. 2. Mass loss (wt%) and heat flux (mW/mg) upon heating of the [Ag(C6F11COO) + Zn] system (DSC measurement in red; mass loss in dashed blue).

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4. Fig. 3. Dependence of the heat of reaction (1) on the mass of silver perfluorocyclohexanoate.

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