Coordination Compounds of Yttrium(III) with Urea and Dimethylacetamide: Composition, Structure, Thermal Behavior

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Abstract

Coordination compounds of yttrium(III) nitrate with urea (Ur) and N,N-dimethylacetamide, [Y(H2O)(Ur)2(NO3)3] (I), [Y(Ur)3(NO3)3] (II) and [Y(DMAA)3(NO3)3] (III), were synthesized; their compositions, structural features and thermolysis were studied with the use of elemental analysis, IR spectroscopy, X-ray powder and single-crystal diffraction, thermal gravimetric analysis, differential scanning calorimetry. The coordination compounds can be used for the synthesis of nano-scale yttrium(III) oxide.

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About the authors

E. K. Bettels

MIREA — Russian Technological University

Email: savinkina@mirea.ru
Russian Federation, Moscow, 119571

M. S. Polukhin

MIREA — Russian Technological University

Email: savinkina@mirea.ru
Russian Federation, Moscow, 119571

I. A. Karavaev

MIREA — Russian Technological University

Email: savinkina@mirea.ru
Russian Federation, Moscow, 119571

E. V. Savinkina

MIREA — Russian Technological University

Author for correspondence.
Email: savinkina@mirea.ru
Russian Federation, Moscow, 119571

G. A. Buzanov

Kurnakov Institute of General and Inorganic Chemistry

Email: savinkina@mirea.ru
Russian Federation, Moscow, 119991

A. S. Kubasov

Kurnakov Institute of General and Inorganic Chemistry

Email: savinkina@mirea.ru
Russian Federation, Moscow, 119991

V. M. Retivov

Kurchatov Institute National Research Center

Email: savinkina@mirea.ru
Russian Federation, Moscow, 123182

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Supplementary files

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2. Appendix
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3. Scheme 1. Scheme for the synthesis of complex compounds I, II and III.

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4. Fig. 1. Diffractograms of precursors and isolated complexes: 1 - Ur, 2 - Y(NO3)3 - 6H2O, 3 - III (exp.), 4 - III (theor.), 5 - I (exp.), 6 - I (theor.), 7 - II (exp.), 8 - II (theor.).

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5. Fig. 2. Molecular structures of complexes I (a), II (b), III (c).

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6. Fig. 3. Thermograms of complexes I (a) and III (b) in air; 1 - mass loss curve, 2 - differential curve.

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7. Fig. 4. Diffraction patterns of Y2O3 preparations obtained by annealing complexes III (1), I (2), II (3) in air.

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