Synthesis, Structure, and Electrochemical Properties of Cobalt Complex Based on N-(2,5-Bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate
- Авторлар: Sakhapov I.F.1, Kagilev A.A.1,2, Kantyukov A.O.1,2, Mikhailov I.K.1,2, Sof’icheva O.S.1, Islamov D.R.3, Gafurov Z.N.1, Yakhvarov D.G.1,2
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Мекемелер:
- Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences
- Alexander Butlerov Institute of Chemistry, Kazan Federal University
- Laboratory for Structural Analysis of Biomacromolecules, FRC Kazan Scientific Center, Russian Academy of Sciences
- Шығарылым: Том 68, № 9 (2023)
- Беттер: 1287-1292
- Бөлім: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
- URL: https://rjraap.com/0044-457X/article/view/666263
- DOI: https://doi.org/10.31857/S0044457X23601098
- EDN: https://elibrary.ru/WOIXFC
- ID: 666263
Дәйексөз келтіру
Аннотация
New bis-chelate cobalt(II) complex [Co(DPG)2(DMF)2] (1), where DPG is N-(2,5-bis(methoxycarbonyl)phenyl)-α-diphenylphosphorylglycinate, has been prepared and characterized. The complex is the first example of cobalt complex containing phosphorylated derivative of α-amino acid. Octahedral coordination geometry of the cobalt complex 1 has been determined by X-ray diffraction. Electrochemical reduction of the obtained complex has been found to be irreversible two-electron process (
= –1.70 V vs Ag/AgNO3, 1 × 10–2 М in CH3CN), resulting in formation of cobalt metal adsorbed on the surface of working electrode.
Авторлар туралы
I. Sakhapov
Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences
Email: ilyas.sakhapov@iopc.ru
420088, Kazan, Russia
A. Kagilev
Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences; Alexander Butlerov Institute of Chemistry, Kazan Federal University
Email: yakhvar@iopc.ru
420088, Kazan, Russia; 420008, Kazan, Russia
A. Kantyukov
Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences; Alexander Butlerov Institute of Chemistry, Kazan Federal University
Email: yakhvar@iopc.ru
420088, Kazan, Russia; 420008, Kazan, Russia
I. Mikhailov
Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences; Alexander Butlerov Institute of Chemistry, Kazan Federal University
Email: yakhvar@iopc.ru
420088, Kazan, Russia; 420008, Kazan, Russia
O. Sof’icheva
Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences
Email: yakhvar@iopc.ru
420088, Kazan, Russia
D. Islamov
Laboratory for Structural Analysis of Biomacromolecules, FRC Kazan Scientific Center, Russian Academy of Sciences
Email: yakhvar@iopc.ru
420011, Kazan, Russia
Z. Gafurov
Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences
Email: yakhvar@iopc.ru
420088, Kazan, Russia
D. Yakhvarov
Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences; Alexander Butlerov Institute of Chemistry, Kazan Federal University
Хат алмасуға жауапты Автор.
Email: yakhvar@iopc.ru
420088, Kazan, Russia; 420008, Kazan, Russia
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