Solid solutions of pyridinium halobismuthates

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Resumo

Solid solutions of pyridinium bromo-iodobismutates were isolated from aqueous solutions and structurally characterized. The composition of the resulting solid solutions [HPy]BiX4 and [HPy]3Bi2X9 (X = Br, I) was found to depend on the ratios of pyridinium/bismuth and bromine/iodine in the initial solution. The existence of five polymorphic modifications in the system for [HPy]BiX4 compounds was shown. Two different polymorphs were found for iodobismuthate [HPy]BiI4.

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Sobre autores

P. Buikin

HSE University; Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Autor responsável pela correspondência
Email: peterzzz@mail.ru
Rússia, 101000, Moscow; 119991 Moscow

A. Zhavoronkov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: peterzzz@mail.ru
Rússia, 119991 Moscow

A. Ilyukhin

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: peterzzz@mail.ru
Rússia, 119991 Moscow

V. Kotov

HSE University; Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: peterzzz@mail.ru
Rússia, 101000, Moscow; 119991 Moscow

Bibliografia

  1. Groom C.R., Bruno I.J., Lightfoot M.P. et al. // Acta Crystallogr., Sect. B: Struct. Sci. Cryst. Eng. Mater. 2016. V. 72. № 2. P. 171. https://doi.org/10.1107/S2052520616003954
  2. Adonin S.A., Gorokh I.D., Novikov A.S. et al. // Chem. — A Eur. J. 2017. V. 23. № 62. P. 15612. https://doi.org/10.1002/chem.201703747
  3. Kotov V.Y., Ilyukhin A.B., Buikin P.A. et al. // Mendeleev Commun. 2019. V. 29. № 5. P. 537. https://doi.org/10.1016/j.mencom.2019.09.020
  4. Robertson B.K., McPherson W.G., Meyers E.A. // J. Phys. Chem. 1967. V. 71. № 11. P. 3531. https://doi.org/ 10.1021/J100870A028/ASSET/J100870A028.FP.PNG_V03
  5. Li T., Hu Y., Morrison C.A. et al. // Sustain. Energy Fuels. 2017. V. 1. № 2. P. 308. https://doi.org/10.1039/c6se00061d
  6. Balabanova S.P., Buikin P.A., Ilyukhin A.B. et al. // Russ. J. Inorg. Chem. 2022. V. 67. № 7. P. 1018. https://doi.org/10.1134/S0036023622070038
  7. Usol’tsev A.N., Shentseva I.A., Shayapov V.R. et al. // Russ. J. Inorg. Chem. 2021. V. 66. № 10. P. 1482. https://doi.org/10.1134/S0036023621100193
  8. Buikin P.A., Ilyukhin A.B., Baranchikov A.E. et al. // Mendeleev Commun. 2018. V. 28. № 5. P. 490. https://doi.org/10.1016/j.mencom.2018.09.012
  9. Li A., Wu M., Zhang J. et al. // Dalton Trans. 2023. V. 52. № 16. P. 5065. https://doi.org/10.1039/D3DT00210A
  10. Hu X., Wang J., Mao W. et al. // ChemistrySelect. 2021. V. 6. № 5. P. 1099. https://doi.org/10.1002/SLCT.202004010
  11. Kotov V.Y., Ilyukhin A.B., Korlyukov A.A. et al. // New J. Chem. 2018. V. 42. № 8. P. 6354. https://doi.org/10.1039/c7nj04948j
  12. Chen Y., Yang Z., Guo C.X. et al. // Eur. J. Inorg. Chem. 2010. № 33. P. 5326. https://doi.org/10.1002/ejic.201000755
  13. Jóźków J., Medycki W., Zaleski J. et al. // Phys. Chem. Chem. Phys. 2001. V. 3. № 15. P. 3222. https://doi.org/10.1039/B102697F
  14. Tarasiewicz J., Jakubas R., Bator G. et al. // J. Mol. Struct. 2009. V. 932. № 1–3. P. 6. https://doi.org/10.1016/J.MOLSTRUC.2009.05.034
  15. Aurivillius B., Stålhandske C., Eriksen T.E. et al. // Acta Chem. Scand. 1978. V. 32a. P. 715. https://doi.org/10.3891/ACTA.CHEM.SCAND.32A-0715
  16. James S.C., Lawson Y.G., Norman N.C. et al. // Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 2000. V. 56. № 4. P. 427 https://doi.org/10.1107/S0108270100000263/AV1032IISUP3.HKL
  17. Adonin S.A., Gorokh I.D., Novikov A.S. et al. // Polyhedron. 2018. V. 139. P. 282. https://doi.org/10.1016/j.poly.2017.11.002
  18. Li S.G., Chen L., Xiang Y. // J. Mol. Struct. 2017. V. 1130. P. 617. https://doi.org/10.1016/j.molstruc.2016.11.025
  19. Möbs J., Gerhard M., Heine J. // Dalton Trans. 2020. V. 49. № 41. P. 14397. https://doi.org/10.1039/D0DT03427D
  20. Brucker // APEX3 2016. Madison.
  21. Sheldrick G.M. // Programs Scaling Absorpt. Correct. Area Detect. Data, 1997.
  22. Sheldrick G.M. // TWINABS 2012/1, Bruker, Madison, Wisconsin, USA, 2012.
  23. Sheldrick G.M. // Acta Crystallogr., Sect. C: Struct. Chem. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053229614024218
  24. Coelho A. // Bruker AXS GmbH 2009.
  25. Kubelka P., Munk F. // Z. Tech. Phys. 1931. V. 12. № 1930. P. 593. http://www.graphics.cornell.edu/~westin/pubs/kubelka.pdf
  26. Kotov V.Y., Lunkov I.S., Buikin P.A. et al. // New J. Chem. 2023. V. 47. № 5. P. 2666. https://doi.org/10.1039/D2NJ05184B
  27. Leblanc N., Mercier N., Allain M. et al. // J. Solid State Chem. 2012. V. 195. P. 140. https://doi.org/10.1016/j.jssc.2012.03.020
  28. Hu Y.Q., Hui H.Y., Lin W.Q. et al. // Inorg. Chem. 2019. V. 58. № 24. P. 16346. https://doi.org/10.1021/acs.inorgchem.9b01439

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2. Fig. 1. Fragment of structure I.

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3. Fig. 2. The dependence of the proportion of iodine in solid solutions (IEDX) on the iodine content in the mother liquor (Isolv) with a different ratio [HPy]+ : Bi3+.

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4. Рис. 3. Зависимость значений оптической ширины запрещенной зоны (Eg) от доли иода в твердых растворах p3–p8 (IEDX). По оси у Еg, эВ.

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