Extraction of Uranyl Tricarbonate Complex by Clay Materials from Aqueous Solutions

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

The processes of extraction of the tricarbonate complex of uranyl [UO2(CO3)3]4– from aqueous solutions on clay powders from kaolin clays of the Kampanovskoye deposit and from bentonite clays of the 10th Khutor and Dinozavrovoe deposits, as well as their mixtures, were investigated. The studies were carried out with clay powders, both untreated and treated with water, solutions of 0.5 mol/l Na2CO3 and NaNO3, and 2 mol/l solutions of NaOH. It has been shown that the [UO2(CO3)3]4- complex is not sorbed on clay materials from aqueous solutions under static conditions. It has been established that filtration of an aqueous solution of [UO2(CO3)3]4- through columns with clay mixtures allows one to extract up to 87% of uranium from the amount passed through the column

Толық мәтін

Рұқсат жабық

Авторлар туралы

E. Krasavina

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Ресей, Leninskii pr. 31, korp. 4, Moscow, 119071

K. Martynov

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Ресей, Leninskii pr. 31, korp. 4, Moscow, 119071

K. Arzumanova

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Ресей, Leninskii pr. 31, korp. 4, Moscow, 119071

A. Bessonov

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Ресей, Leninskii pr. 31, korp. 4, Moscow, 119071

A. Gordeev

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Ресей, Leninskii pr. 31, korp. 4, Moscow, 119071

A. Bomchuk

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Ресей, Leninskii pr. 31, korp. 4, Moscow, 119071

V. Zharkova

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Ресей, Leninskii pr. 31, korp. 4, Moscow, 119071

S. Kulyukhin

Frimkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: kulyukhin@ipc.rssi.ru
Ресей, Leninskii pr. 31, korp. 4, Moscow, 119071

Әдебиет тізімі

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Әрекет
1. JATS XML
Жүктеу
2. 1. Modified clay KGPO-23 (1 – KGPO-23-W, 2 – KGPO-23-Carb, 3 – KGPO-23-Az, 4 – KGPO-23-W-Alk, 5 –KGPO-23-Carb-Alk, 6 – KGPO-23-Az-Alk; K – kaolinite, Al2Si2O5(OH)4 [11], Q – quartz [12], F – potassium feldspar, KAlSi3O8 [13], Il – illite, KAl3Si3O10(OH)2 [14], Na-Al – sodium aluminate, Na5AlO4 [19], Na-Si – sodium silicate, Na2Si2O5⋅5H2O [20]).

Жүктеу (249KB)
Метадеректер
3. 2. Modified clay kgpo-28 (1 – kgpo-28-W, 2 – kgpo-28-Carb, 3 –kgpo-28-az, 4 – kgpo-28-W-ALK, 5 –kgpo-28-Carb-ALK, 6 – kgpo-28-az-ALK; K – kaolinite, al2si2o5(Oh)4 [11], Q – quartz [12], F – potassium feldspar, KALSI3O8 [13], IL – Illite, KAL3SI3O10(OH)2 [14], Na-si – aqueous sodium silicate, NA2SIO3⋅5H2O [21], K-si – potassium silicate, K4(H4SI4O12) [23]).

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Метадеректер
4. Pain. 3. Modified HBGP clay (1 – HBGP-W, 2 – HBGP-Carb, 3 – HBGP-Az, 4 – HBGP-W-Alk, 5 – HBGP-Carb-Alk, 6 – HBGP-Az-Alk; Q – quartz [12], F – potassium feldspar, KAlSi3O8 [13], Na-Mt – montmorillonite in the Na-form, namgalsio2(OH)⋅H2O [15], CA-Mt –montmorillonite in Ca form, CA0.2(Al, Mg)2SI4O10(oh)2⋅4H2O [16], Il-Mt–Illite-montmorillonite, kal4(Si, Al)8o20(Oh)4⋅xh2o [17], C – calcite, CaCO3 [18], Na-si – aqueous sodium silicate, Na2sio3⋅5H2O [21], Na-SI1 – sodium hydrosilicate, Nahsi2o5 [22], na-Si2 – aqueous sodium silicate, na2si2o5⋅5h2o [20]).

Жүктеу (220KB)
Метадеректер
5. 4. Modified clay DB (1 – DB-W, 2–DB-Carb, 3– DB-Az, 4– DB-W-Alk, 5– DB-Carb-Alk, 6–DB-Az-Alk; Q –quartz [12], Na-Mt – montmorillonite in Na form, NaMgAlSiO2(OH)⋅H2O [15], Ca-Mt –montmorillonite in Ca form, Ca0.2(Al, Mg)2Si4O10(OH)2⋅4H2O [16], Il-Mt – illite-montmorillonite, KAl4(Si, Al)8O20(OH)4⋅xH2O [17], C – calcite, CaCO3 [18], Na-Al – sodium aluminate, Na5AlO4 [19], Na-Si – aqueous sodium silicate, Na2SiO3⋅5H2O [21], Crb – aqueous sodium carbonate Na2CO3⋅H2O [22]).

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Метадеректер
6. Fig. 5. Photograph of columns with clay material in the process of saturation with a solution of [UO2(CO3)3]4– and filtration of the solution (a – columns with an unconsolidated air-dry mixture of clay materials; b–d – view of a column with clay material in the process of saturation with a solution of [UO2(CO3)3]4– and filtration of the solution after 45 min (b), 70 h (c), 120 h (d); e – the type of columns at the initial moment of washing with distilled water; mixtures of clay materials (in mass ratio 1 : 1) in columns: 1 – KGPO-28/DB, 2 – KGPO-23/HBGP, 3 – KGPO-28/HBGP, 4 – KGPO-23/DB).

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7. Fig. 6. Change in the height of the water layer above the wet clay material through which the solution [UO2(CO3)3]4–was previously passed. (Mixtures of clay materials (in mass ratio 1 : 1) in columns: 1 – KGPO-28/DB, 2 – KGPO-23/HBGP, 3 – KGPO-28/HBGP, 4 – KGPO-23/DB).

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