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An Increase in The Cross-Section of Two-Photon Absorption of Styrene Dye in Supramolecular Complexes with Cucurbituriles
- Authors: Petrov N.H.1,2, Ivanov A.A.1,3, Ivanov D.A.1, Fedotov A.B.3, Lanin A.А.3, Chebotarev A.S.3
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Affiliations:
- Crystallography and Photonics Federal Research Center of the Russian Academy of Sciences
- Moscow Institute of Physics and Technology (National Research University)
- Lomonosov Moscow State University
- Issue: Vol 58, No 3 (2024)
- Pages: 198-202
- Section: PHOTONICS
- URL: https://rjraap.com/0023-1193/article/view/661344
- DOI: https://doi.org/10.31857/S0023119324030033
- EDN: https://elibrary.ru/UUSJPZ
- ID: 661344
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Abstract
Two-photon absorption cross sections of aqueous solutions of the styryl dye trans-4-[4-(dimethylamino)styryl]-1-methylpyridinium iodide (DASPI) and its inclusion complexes with cucurbit[n]urils (CB[n] n = 6–8) were measured using fluorescence spectroscopy. A nonmonotonic dependence of the cross-section size on the excitation wavelength and on the cavitand cavity size was found. Compared with a free dye, a sevenfold increase in the two-photon absorption cross section was observed in DASPI inclusion complexes with CB[8] at an excitation wavelength of 980 nm.
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About the authors
N. H. Petrov
Crystallography and Photonics Federal Research Center of the Russian Academy of Sciences; Moscow Institute of Physics and Technology (National Research University)
Email: ivanovd@photonics.ru
Russian Federation, Moscow; Dolgoprudny
A. A. Ivanov
Crystallography and Photonics Federal Research Center of the Russian Academy of Sciences; Lomonosov Moscow State University
Email: ivanovd@photonics.ru
Russian Federation, Moscow; Moscow
D. A. Ivanov
Crystallography and Photonics Federal Research Center of the Russian Academy of Sciences
Author for correspondence.
Email: ivanovd@photonics.ru
Russian Federation, Moscow
A. B. Fedotov
Lomonosov Moscow State University
Email: ivanovd@photonics.ru
Russian Federation, Moscow
A. А. Lanin
Lomonosov Moscow State University
Email: ivanovd@photonics.ru
Russian Federation, Moscow
A. S. Chebotarev
Lomonosov Moscow State University
Email: ivanovd@photonics.ru
Russian Federation, Moscow
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