Testing the possibility of using desiccators to study the aerosol effect of liquid deicing material

Cover Page

Cite item

Full Text

Abstract

Introduction. In many countries, there is an additional group of pollutants – deicing materials (DIM) in winter. Salt-containing DIM is one of the factors for increasing the content of PM2.5 and PM10 in the air. The purpose was to determine the possibility of using desiccators to study the aerosol effect of liquid deicing material, identify the chemical composition in the air at spreading liquid DIM in various ways, and establish the calculated doses for conducting a toxicological experiment to study the DIM aerosol effect on the organism of warm-blooded animals.

Materials and methods. A model experiment was conducted in airtight containers (desiccators) using a liquid DIM that includes NaCl and CaCl2. All chemical compounds were captured in air pumping from the desiccator into a bubbler tank with bidistilled water and then analyzed using ion chromatography.

Results. When comparing the obtained results of main DIM components contained in the air inside desiccators with the maximum permissible concentrations, the excess of Cl- was detected both for the highest single concentration of 0.1 mg/m3 and for the average daily concentration of 0.03 mg/m3. When applying DIM at a dose exceeding ten times the recommended norms for liquid the DIM, an excess level of the maximum permissible concentration for chlorine (but not for sodium and calcium) is observed.

Conclusion. The method of DIM studying in desiccators is indicative in terms of the choice of concentrations and studying mechanisms of reagent intake for subsequent DIM research conduction using laboratory animals.

About the authors

Olga V. Ushakova

Centre for Strategic Planning and Management of Biomedical Health Risks of the Federal Medical Biological Agency

Author for correspondence.
Email: noemail@neicon.ru
ORCID iD: 0000-0003-2275-9010
Russian Federation

Irina S. Evseeva

Centre for Strategic Planning and Management of Biomedical Health Risks of the Federal Medical Biological Agency

Email: noemail@neicon.ru
ORCID iD: 0000-0001-5765-0192
Russian Federation

Lev I. Tribis

Centre for Strategic Planning and Management of Biomedical Health Risks of the Federal Medical Biological Agency

Email: ltribis@cspmz.ru
ORCID iD: 0000-0002-1687-4162

Ph.D., chemist of the Federal Centre for Strategic Planning and Management of Biomedical Health Risks» of the Federal Medical Biological Agency, Moscow, 119121, Russian Federation.

e-mail: ltribis@cspmz.ru; tribislev@hotmail.com

Russian Federation

Anton V. Sbitnev

Centre for Strategic Planning and Management of Biomedical Health Risks of the Federal Medical Biological Agency

Email: noemail@neicon.ru
ORCID iD: 0000-0003-4406-4287
Russian Federation

Mariya A. Vodyanova

Centre for Strategic Planning and Management of Biomedical Health Risks of the Federal Medical Biological Agency

Email: noemail@neicon.ru
ORCID iD: 0000-0003-3350-5753
Russian Federation

References

  1. Croft D.P., Zhang W., Lin S., Thurston S.W., Hopke P.K., Masiol M., et al. The association between respiratory infection and air pollution in the setting of air quality policy and economic change. Ann. Am. Thorac. Soc. 2019; 16(3): 321–30. https://doi.org/10.1513/annalsats.201810-691oc
  2. Vallero D. Fundamentals of Air Pollution. 5th ed. Academic Press; 2014.
  3. Vodyanova M.A., Ushakova O.V., Doner’yan L.G., Evseeva I.S. The problem of application and assessment of deicing agents in the conditions of megapolis. Sovremennye problemy nauki i obrazovaniya. 2018; (5): 53–61. https://doi.org/10.17513/spno.28059 (in Russian)
  4. Antropova N.S., Vodyanova M.A., Sbitnev A.V., Abramov E.G., Sereda A.E. Assessment of methods for chemical analysis of winter atmospheric air when applying deicing materials. Chem. Saf. Sci. 2019; 3(1): 83–95. https://doi.org/10.25514/CHS.2019.1.15011
  5. Kundu S., Stone E.A. Composition and sources of fine particulate matter across urban and rural sites in the Midwestern United States. Environ. Sci. Process Impacts. 2014; 16(6): 1360–70. https://doi.org/10.1039/c3em00719g
  6. Gertler A., Kuhns H., Abu-Allaban M., Damm C., Gillies J., Etyemezian V., et al. A case study of the impact of Winter road sand/salt and street sweeping on road dust re-entrainment. Atmos. Environ. 2006; 40(31): 5976–85.
  7. Mussato B.T., Gepraegs O.K., Seabrook P.T., Davidson J.P., Charlton R.S., Parker R.D., et al. Guidelines for the Selection of Snow and Ice Control Materials to Mitigate Environmental Impacts. Washington, D.C.: Transportation Research Board; 2007. Available at: https://www.nap.edu/catalog/23178
  8. Particle Pollution and Respiratory Effects. United States Environmental Protection Agency; 2017. Available at: https://www.epa.gov/particle-pollution-and-your-patients-health/health-effects-pm-patients-lung-disease
  9. Casey P.C., Alwan C.W., Kline C.F., Landgraf G.K., Linsenmayer K.R. Impacts of using salt and salt brine for roadway deicing. Idaho Transportation Department. Report No.: FHWA-ID-14-231; 2014. Available at: https://apps.itd.idaho.gov/apps/research/Completed/RP231.pdf
  10. Nixon W.A., Williams A.D. A guide for selecting anti-icing chemicals. Version 1.0. Iowa City: IIHR-Hydroscience and Engineering College of Engineering, The University of Iowa; Report No.: 420; 2001. Available at: https://pdfs.semanticscholar.org/c0dd/250c037a1f3b3d18dfa6290aef0164d1aba7.pdf
  11. Chang N.Y., Brady B., Oncul F., Gottschalk T., Gleason E., Oravez D., et al. Cost of Sanding. Denver: Colorado Department of Transportation Research Branch; Report No.: CDOT-DTD-R-2002-5; 2002. Available at: https://www.codot.gov/admin/programs/research/pdfs/2002/sanding.pdf
  12. Gotovskiy D.G. Studies of toxicity, biocidal properties and efficiency of “Dezolyuks” disinfectant. Uchenye zapiski uchrezhdeniya obrazovaniya Vitebskaya ordena Znak pocheta gosudarstvennaya akademiya veterinarnoy meditsiny. 2019; 55(2): 105–9. (in Russian)
  13. Vasil’kevich V.M., Sobol’ Yu.A., Filonov V.P. Some aspects of the experimental studies and hygienic assessment of disinfectants used in healthcare organizations and food industry. Zdorov’e i okruzhayushchaya sreda. 2016; (26): 210–3. (in Russian)
  14. Chudakova S.B. Toxicological and hygienic evaluation of the degree of danger anti-icing reagents: Diss. Moscow; 2006. (in Russian)
  15. Alikbaeva L.A., Mokrousova O.N., Merkur’eva M.A., Bek A.V., Sadchenko V.Yu. Toxicological-hygienic characteristics of chlorine-containing deicing materials. Profilakticheskaya i klinicheskaya meditsina. 2014; (4): 25–9. (in Russian)
  16. Ofitserov M.L., Zabolotskaya T.V. The study of acute and chronic toxicity deicing composition «Ekotrek». Interaktivnaya nauka. 2016; (2): 18–21. (in Russian)
  17. Vodyanova M.A., Kryatov I.A., Chudakova S.B., Ushakova O.V., Evseeva I.S., Makoveckaya A.K., et al. Evaluation of allergenic, immunogenic and skin irritant effects of anti-ice reagents on the body of warm-blooded animals. Bull. Exp. Biol. Med. 2019; 167(5): 656–9. https://doi.org/10.1007/s10517-019-04592-z
  18. Kryatov I.A., Tonkopiy N.I., Vodyanova M.A., Rusakov N.V., Doner’yan L.G., Evseeva I.S., et al. Methodical approaches to the substantiation of hygienic requirements for the application of deicing materials. Gigiena i Sanitaria (Hygiene and Sanitation, Russian journal). 2014; 93(6): 52–4. (in Russian)
  19. R 4.2.2643-10. Methods of laboratory researches and tests of disinfectants to assess their effectiveness and safety. Moscow; 2010. (in Russian)
  20. Technology of winter cleaning of the carriageway of highways, streets, driveways and squares (objects of road facilities of Moscow) with the use of deicing materials and crushed granite of 2–5 mm fraction (for winter periods from 2010–2011 and further); 2011. Available at: https://www.mos.ru/dgkh/documents/deistvuiushchie-normativnye-pravovye-akty/view/40392220/ (in Russian)
  21. GOST 31867-2012. Drinking water. Anions content determination by chromatography and capillary electrophoresis. Moscow; 2014. (in Russian)
  22. FR 1.31.2008.01738. Method for measuring the mass concentration of cations of ammonium, potassium, sodium, magnesium, calcium and strontium in samples of drinking, mineral, canteen, medical-canteen, natural and waste water by ion chromatography. Moscow; 2008. (in Russian)
  23. GN 2.1.6.3492-17. Maximum permissible concentrations (MPC) of pollutants in the atmospheric air of urban and rural settlements. Moscow; 2018. (in Russian)
  24. Kuts V.P., Slobodyan S.M. Analysis method for disperse composition of aerosols, dusts and powders. Izvestiya Altayskogo gosudarstvennogo universiteta. 2014; (1–1): 248–51. https://doi.org/10.14258/izvasu(2014)1.1-55 (in Russian)

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2024 Ushakova O.V., Evseeva I.S., Tribis L.I., Sbitnev A.V., Vodyanova M.A.



СМИ зарегистрировано Федеральной службой по надзору в сфере связи, информационных технологий и массовых коммуникаций (Роскомнадзор).
Регистрационный номер и дата принятия решения о регистрации СМИ: серия ПИ № ФС 77 - 37884 от 02.10.2009.