电邮这篇文章 Reaction operator in the main equation of spin chemistry
- 作者: Purtov P.A.1,2
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隶属关系:
- Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences
- Novosibirsk State University
- 期: 卷 43, 编号 2 (2024)
- 页面: 3-8
- 栏目: Элементарные физико-химические процессы
- URL: https://rjraap.com/0207-401X/article/view/674981
- DOI: https://doi.org/10.31857/S0207401X24020016
- EDN: https://elibrary.ru/WJASAT
- ID: 674981
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详细
In our previous works, using an exactly solvable model as an example, we demonstrated the validity of the reaction operator in the basic equation of spin chemistry. However, in these works, only recombination from the singlet state was considered. Although the general relations allowed us to consider the general case. In the present paper, such a general case is analyzed. The radical pair comes into contact in a mixed singlet-triplet state, and recombination proceeds from both the singlet and triplet states. The result obtained fully corresponds to the basic equation of spin chemistry.
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作者简介
P. Purtov
Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
编辑信件的主要联系方式.
Email: purtov@kinetics.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk
参考
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补充文件
注意
Х Международная конференция им. В.В. Воеводского “Физика и химия элементарных химических процессов” (сентябрь 2022, Новосибирск, Россия).