Extraction Of Actinides And Lanthanides From Nitric Acid Solutions With Mixtures of 1,5-N,N′- Bis[(Diphenylphosphoryl)Acetyl(Hexyl)Amino]Pentane And New Asymmetrical Phosphonium- And Imidazolium Based Ionic Liquid

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A new dicationic ionic liquid 1-methyl-3-(4-(tributylphosphonio)butyl)-1H-imidazol-3-ium di[bis(trifluoromethanesulfonul)imide] [ImP][Tf2N]2, characterized by high hydrophobicity (solubility in water 9.2 × 10-4 mol/l) was synthesized. The extraction of U(VI), Th(IV), and lanthanides(III) from nitric acid solutions with mixtures of 1,5-N,N’-bis[(diphenylphosphoryl)acety(hexyl)amino]pentane (L), containing two bidentate fragments Ph2P(O)CH2C(O)N(Hex)- interconnected by pentamethylene spacer through amide nitrogen atoms, and [ImP][Tf2N]2 in 1,2-dichloroethane (DCE) was studied. During the extraction of metal ions in this system, a significant synergistic effect is observed. The influence of the composition of the aqueous and organic phases on the efficiency of the extraction of metal ions into the organic phase is considered, and the stoichiometry of the extracted complexes is determined. The synergistic effect at the extraction of Ln(III) from 3 M HNO3 solutions with a mixture of L and [ImP][Tf2N]2 in DCE is an order of magnitude higher than in the L–[C8mim][Tf2N]–DCE system.

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作者简介

A. Turanov

Yu.A. Ossipyan Institute of Solid State Physics of the Russian Academy of Sciences

Email: sharovaev@mail.ru
俄罗斯联邦, Chernogolovka, 142432

V. Karandashev

Institute of Microelectronics Technology and High-Purity Materials of the Russian Academy of Sciences

Email: sharovaev@mail.ru
俄罗斯联邦, Chernogolovka, 142432

E. Sharova

A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: sharovaev@mail.ru
俄罗斯联邦, Moscow, 119334

O. Artyushin

A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Email: sharovaev@mail.ru
俄罗斯联邦, Moscow, 119334

参考

  1. Welton T. // Chem. Rev. 1999. V. 99. P. 2071. https://doi.org/10.1021/cr980032t
  2. Nosov D., Ronnasi B., Lozinskaya E.I. et al. // ACS Appl. Polym. Mater. 2023. V. 5. № 4. P. 2639. https://doi.org/10.1021/acsapm.2c02223
  3. Ponkratov D.O., Shaplov A.S., Vygodskii Ya.S. // Polym. Sci. Ser. C. 2019. V. 61. № 1. P. 2. https://doi.org/10.1134/S1811238219010144
  4. Wang W., Murray R.W. // Anal. Chem. 2007. V. 79. № 3. P. 1213. https://doi.org/10.1021/ac0615697
  5. Berthod A., Ruiz-Angel M.J., Carda-Broch S. // J. Chromatogr. A. 2008. V. 1184. P. 6. https://doi.org/10.1016/j.chroma.2007.11.109
  6. Kamaz M., Vogler R.J., Jebur M. et al. // Sep. Purif. Technol. 2020. V. 236. P. 116237. https://doi.org/10.1016/j.seppur.2019.116237
  7. Atanassova M. // J. Mol. Liq. 2021. V. 343. P. 117530. https://doi.org/10.1016/j.molliq.2021.117530
  8. Iqbal M., Waheed K., Rahat S.B. et al. // J. Radioanal. Nucl. Chem. 2020. V. 325. P. 1. https://doi.org/10.1007/s10967-020-07199-1
  9. Arrachart G., Couturier J., Dourdain S. et al. // Processes. 2021. V. 9. P. 1202. https://doi.org/10.3390/pr9071202
  10. Белова В.В. // Радиохимия. 2021. Т. 63. № 1. С. 3. https://doi.org/10.31857/S0033831121010019 Belova V.V. // Radiochemistry. 2021. V. 63. № 1. P. 1. https://doi.org/10.1134/S106636222101001X
  11. Sun. X., Luo H., Dai S. // Chem. Rev. 2012. V. 112. № 4. P. 2100. https://doi.org/10.1021/cr200193x
  12. Turanov A.N., Karandashev V.K., Baulin V.E. // Solvent Extr. Ion Exch. 2012. V. 30. P. 244. http://dx.doi.org/10.1080/07366299.2011.639248
  13. Turanov A.N., Karandashev V.K., Sharova E.V. et al. // Radiochim. Acta. 2018. V. 106. P. 355. https://doi.org/10.1515/ract-2017-2851
  14. Turanov A.N., Karandashev V.K., Boltoeva M. et al. // Sep. Purif. Technol. 2016. V. 164. P. 97. http://dx.doi.org/10.1016/j.seppur.2016.03.004
  15. Gan Q., Cai Y., Fu K. et al. // Radiochim. Acta. 2020. V. 108. P. 239. https://doi.org/10.1515/ract-2019-3147
  16. Luo H., Dai S., Bonnesen P.V. et al. // Solvent Extr. Ion Exch. 2006. V. 24. P. 19. https://doi.org/10.1080/07366290500388624
  17. Sun T., Zhang Y., Wu Q. et al. // Solvent Extr. Ion Exch. 2017. V. 35. P. 408. https://doi.org/10.1080/07366299.2017.1379142
  18. Cho C.-W., Phan T.P.T., Zhao Y. et al. // Sci. Total Environ. 2021. V. 786. P. 147309. https://doi.org/10.1016/j.scitotenv.2021.147309
  19. Montalban M.G., Villora G., Licence P. // Ecotoxicol. Environ. Saf. 2018. V. 150. P. 129. https://doi.org/10.1016/j.ecoenv.2017.11.073
  20. Anderson J.I., Ding R., Ellern A., Armstrong D.W. // J. Am. Chem. Soc. 2005. V. 127. P. 593. https://doi.org/10.1021/ja046521u
  21. Shirota H., Mandai T., Fukazawa H., Kato T. // J. Chem. Eng. Data. 2011. V. 56. P. 2453. https://doi.org/10.1021/je2000183
  22. Hawker R.R., Haines R.S., Harper J.B. // Chem. Commun. 2018. V. 54. P. 2296. https://doi.org/10.1039/c8cc00241
  23. Arkhipova E.A., Ivanov A.S., Levin M.M. et al. // J. Mol. Liq. 2022. V. 346. P. 117095. https://doi.org/10.1016/j.molliq.2021.117095
  24. Turanov A.N., Karandashev V.K., Sharova E.V. et al. // Solvent Extr. Ion Exch. 2012. V. 30. P. 604. https://doi.org/10.1080/07366299.2012.671117
  25. Туранов А.Н., Карандашев В.К., Харитонов А.В. и др. // Журн. общей химии. 1999. Т. 69. № 7. С. 1109.
  26. Bonhote P., Dias A. P., Papageorgiou N. et al. // Inorg. Chem. 1996. V. 35. P. 1168. https://doi.org/10.1021/ic951325x
  27. Rothstein E., Saville R.W., Horn P.E. // J. Chem. Soc. 1953. P. 3994. https://doi.org/10.1039/JR9530003994
  28. Карандашев В.К., Лейкин А.Ю., Хвостиков В.А. и др. // Заводская лаборатория. Диагностика материалов. 2015. Т. 81. № 5. С. 5.
  29. Toh S.L.I., McFarlane J., Tsouris C. et al. // Solvent Extr. Ion Exch. 2006. V. 24. P. 33. https://doi.org/10.1080/07366290500388400
  30. Rozen A.M., Krupnov B.V. // Russ. Chem. Rev. 1996. V. 65. P. 973. https://doi.org/10.1070/RC1996v065n11ABEH000241
  31. Binnemans K. // Chem. Rev. 2007. V. 107. P. 2592. https://doi.org/10.1021/cr050979c
  32. Dam H.H., Reinhoudt D.N., Verboom W. // Chem. Soc. Rev. 2007. V. 36. P. 367. https://doi.org/10.1039/b603847f
  33. Horwitz E.P., Martin K.A., Diamond H., Kaplan L. // Solvent Extr. Ion Exch. 1986. V. 4. P. 449. https://doi.org/10.1080/07366298608917877

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2. Fig. 1. Effect of HNO3 concentration in the aqueous phase on the extraction of Th(IV) (1, 4), U(VI) (2, 5) and Eu(III) (3, 6) with solutions of compound L in dichloroethane (4-6) and in dichloroethane containing 0.003 M IL [ImP][Tf2N]2 (1-3). Concentration L, mol/l: 0.0001 (1, 4), 0.0005 (2, 5), 0.002 (3, 6).

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3. Fig. 2. Distribution coefficients of lanthanides(III) during extraction from solutions of 3 M HNO3 with solutions of compounds L (1, 2, 5) and CMFO Ph2Bu2 (3, 4, 6) in dichloroethane (5, 6) and dichloroethane containing 0.025 M [ImP][Tf2N]2 (1, 3) and [C8mim][Tf2N] (2, 4). The concentration of the compound is L 0.01 mol/l, CMFO Ph2Bu2 0.02 mol/L.

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4. 3. Effect of the concentration of compound L in dichloroethane containing 0.002 M [ImP][Tf2N]2 on the extraction of Th(IV), U(VI) and Ln(III) from solutions of 1 M HNO3.

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5. Fig. 4. Effect of the concentration of [ImP][Tf2N]2 in dichloroethane containing 0.002 M of compound L on the extraction of Ln(III) from a solution of 1 M HNO3.

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6. Fig. 5. Effect of [ImP]Br2 concentration in the aqueous phase on the extraction of Ln(III) from 0.01 M HNO3 solutions with 0.002 M solutions of the L compound in dichloroethane containing 0.002 M [ImP][Tf2N]2.

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7. Scheme

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